In this room there are four 17th-century Tuscan paintings, including Saint Girolamo and the penitent Magdalene attributed to the Sienese Bernardino Mei, and a canvas by an anonymous artist with the Virgin who gives the Scapular to Saint Simone Stock. Of particular interest is the canvas that was placed on an altar of the Confraternity of the Trinitarians built in 1656 by the Company of the Madonna della Croce.